Improving Low-temperature Performance and Stability of Na2Ti6O13 Anodes by the Ti−O Spring Effect through Nb-doping

Na₂Ti₆O₁₃ (NTO) with high safety has been regarded as a promising anode candidate for sodium-ion batteries. In the present study, integrated modification of migration channels broadening, charge density re-distribution, and oxygen vacancies regulation are realized in case of Nb-doping and have obtained significantly enhanced cycling performance with 92 % reversible capacity retained after 3000 cycles at 3000 mA g⁻¹. Moreover, unexpected low-temperature performance with a high discharge capacity of 143 mAh g⁻¹ at 100 mA g⁻¹ under −15 °C is also achieved in the full cell. Theoretical investigation suggests that Nb preferentially replaces Ti3 sites, which effectively improves structural stability and lowers the diffusion energy barrier. What's more important, both the in situ X-ray diffraction (XRD) and in situ Raman furtherly confirm the robust spring effect of the Ti−O bond, making special charge compensation mechanism and respective regulation strategy to conquer the sluggish transport kinetics and low conductivity, which plays a key role in promoting electrochemical performance.     

Maneuver analysis methodology to predict vehicle impacts on training lands

Tactical mobility analysis techniques were merged with land management strategies to assess potential impacts of vehicle operations on training areas for rangeland planning and management. A vehicle mobility analysis was performed for a suite of vehicle types using the NATO Reference Mobility Model (NRMM II). Input parameters include terrain information (soil type, slope, vegetation, surface roughness, soil strength), terrain surface condition based on climate (terrain strength, freeze–thaw, moisture content, snow cover), and vehicle specifications (tire, power train, weight on each axle, ground clearance, dimensions, ride). The vehicle performance was spatially mapped over the terrain for different seasons of the year and used to calculate the maneuverable acreage, which was compared to acreage needed for training requirements. This can be related to land capability based on expected training impact (Maneuver Impact Miles, MIM) and Land Condition Curves which link training density to land condition. This methodology can be used to determine the suitability of training lands and the degree of land management or rehabilitation expected. The methodology was applied to the transformation of the Alaska training lands to support a new brigade unit called the Stryker Brigade Combat Team (SBCT3), but is equally useful for other training areas and military units. For summer use, Alaska training lands are capable of supporting four times the projected training requirements. For winter, when the ground is frozen, more than 10 times the area needed was available.     

Dynamic operation modes of AFM: Non-linear behavior and theoretical analysis of the stability of the AFM oscillator

The first part of this paper gives a theoretical study of the mechanics of contact of an AFM tip on viscous materials. Analytical expressions are derived showing the non-linear behaviors specifically related to the use of dynamic operation modes of AFM on viscous materials. A detailed analysis of the dissipated energy as a function of the tip indentation is presented. The second part is dedicated to a theoretical analysis investigating the domain of stability of the oscillator and the influence of the machine. The theoretical approach includes the electronic feedback loop used with the frequency modulation mode. Because the interaction between the tip and the sample produces a dynamical non-linear behavior, an unstable branch occurs that can change the stability of the oscillator. In particular, a sudden jump of the oscillating tip can be produced. In spite of the complexity of the problem, the analytical approach ends with two simple equations. The two equations provide an unambiguous way of discriminating between the contributions from the machine and the tip sample interaction.     

Periodic sticking motion in a two-degree-of-freedom impact oscillator

Periodic sticking motions can occur in vibro-impact systems for certain parameter ranges. When the coefficient of restitution is low (or zero), the range of periodic sticking motions can become large. In this work the dynamics of periodic sticking orbits with both zero and non-zero coefficient of restitution are considered. The dynamics of the periodic orbit is simulated as the forcing frequency of the system is varied. In particular, the loci of Poincaré fixed points in the sticking plane are computed as the forcing frequency of the system is varied. For zero coefficient of restitution, the size of the sticking region for a particular choice of parameters appears to be maximized. We consider this idea by computing the sticking region for zero and non-zero coefficient of restitution values. It has been shown that periodic sticking orbits can bifurcate via the rising/multi-sliding bifurcation. In the final part of this paper, we describe three types of post-bifurcation behavior which occur for the zero coefficient of restitution case. This includes two types of rising bifurcation and a border orbit crossing event.     

Effect of magnetic field on electron spectrum and probabilities of intraband quantum transitions in spherical quantum-dot-quantum-well

The effect of magnetic field on electron energy spectrum, wave functions and probabilities of intraband quantum transitions in multilayered spherical quantum-dot-quantum-well (QDQW) CdSe/ZnS/CdSe/ZnS is studied. Computations are performed in the framework of the effective mass approximation and rectangular potential barriers model. The wave functions are expanded over the complete basis of functions obtained as exact solutions of the Schrodinger equation for the electron in QDQW without the magnetic field.It is shown that magnetic field takes off the spectrum degeneration with respect to the magnetic quantum number and changes the localization of electron in the nanostructure. The field stronger effects on the spherically-symmetric states, especially in the case of electron location in the outer potential well. The magnetic field changes more the radial distribution of probability of electron location in QDQW than the angular one. The oscillator strengths of intraband quantum transitions are calculated as functions of the magnetic field induction and their selection rules are established.     

高功率准分子激光主振荡功率放大系统光学元件的稳定性

为了分析高功率准分子激光主振荡功率放大(MOPA)系统中各光学元件稳定性对靶面光斑定位精度的影响,建立了分析模型,利用分析结果指导高稳定性镜架设计以满足系统实验需求。根据高功率准分子激光MOPA系统特点,有效地简化了系统光路,建立了系统光路模型;按照系统打靶精度要求,利用三维坐标变换和光线追迹法,计算得到了系统单个光学元件稳定性对靶面光斑定位精度的影响规律;最后,对自行设计的镜架进行了稳定性测量。计算结果表明,反射镜的旋转变化和透镜垂直光轴的平移变化是影响靶面光斑定位精度的主要因素,且主放大光路中反射镜在X方向和Y方向上最大的变化范围分别不能超过0.8和1.6μrad。实际测量结果表明,设计的镜架在X方向和Y方向最大的变化范围分别为0.6和0.81μrad,满足系统实验要求。     

Effect of sp-hybridized defects on the oscillatory behavior of carbon nanotube oscillators

Using molecular dynamics simulations, we investigate the oscillatory behaviors of carbon nanotube oscillators containing sp³-hybridized defects formed by hydrogen chemisorption. It is found that the presence of these defects significantly affects the kinetic and potential energies of the nanotube systems, which in turn affects their oscillation periods and frequencies. We have also studied the oscillatory characteristics of the oscillators containing sp³-hybridized Stone-Wales defects. Our results show that it is possible to control the motion of the inner nanotube by introducing sp³-hybridized defects on the outer nanotube, which provides a potential way to tune the oscillatory behavior of nanotube oscillators.     

Dynamics of a delayed two-coupled oscillator with excitatory-to-excitatory connection

In this paper, we consider a neural network model consisting of two coupled oscillators with delayed feedback and excitatory-to-excitatory connection. We study how the strength of the connections between the oscillators affects the dynamics of the neural network. We give a full classification of all equilibria in the parameter space and obtain its linear stability by analyzing the characteristic equation of the linearized system. We also investigate the spatio-temporal patterns of bifurcated periodic oscillations by using the symmetric bifurcation theory of delay differential equations combined with representation theory of Lie groups. Moreover, the stability and bifurcation direction of the bifurcated periodic solutions are obtained by employing center manifold reduction and normal form theory. Some numerical simulations are provided to illustrate the theoretical results.     

Theoretical calculation of electron impact widths and shifts of XeII lines

Summary The shifts and widths of prominent XeII transitions are calculated in the semi-empirical approach; a very good agreement with experimental values is obtained. The oscillator strengths were calculated using complete intermediate coefficients after energy matrix diagonalization. The author of this paper has agreed to not receive the proofs for correction.